Pengaruh variasi komposisi MnFe2O4 terhadap sifat magnetik nanokomposit MnFe2O4/PANi yang disintesis dengan metoda sol – gel spin coating (MnFe2O4 composition influence on the magnetic properties of MnFe2O4 / PANi nanocomposites synthesized by the sol-gel spin coating method)

Zhafrandy Senida - Jurusan Fisika, Universitas Negeri Padang, Sumatera Barat, Indonesia
- Ramli - Jurusan Fisika, Universitas Negeri Padang, Sumatera Barat, Indonesia
- Ratnawulan - Jurusan Fisika, Universitas Negeri Padang, Sumatera Barat, Indonesia
- Hidayati - Jurusan Fisika, Universitas Negeri Padang, Sumatera Barat, Indonesia

Abstract


Currently theeprogressoof material nanocomposite can be applied for some of electronic device, bio medic, and electronic engineering. This is because nanocomposite has multifunction of magnetic properties. Most of device use nanoparticles was made from ferrite material, such as MnFe2O4 with high electrical performance, high magnetic permeability. And as matrix used PANi with good thermal stability and high conductivity. With this advantages, synthesis both material can be applied for electronic device like magnetic sensor. Synthesis MnFe2O4/PANi nanocomposite material with 30%, 40%, 50%, 60%, and 70% composition variation of MnFe2O4 with Sol-Gel method has been success. MnFe2O4/PANi nanocomposite was prepared by make of Fe2O3 precursor, make MnFe2O4 and PANi solution with sol-gel method, make MnFe2O4/PANi nanocomposite with spin coating, heating, and sintering the nanocomposite. This nanocomposite characterized with XRD, FTIR, and VSM. Magnetic properties nanocomposite were measured withaa Vibrating Sample Magnetometer (VSM). Result of VSM shows value of coercivity (Hc), remanence magnetization (Mr) and saturation magnetization (Ms). Highest value offcoercivity shows in 60% composition variation with score 389,99Oe, from the value of coercivity, we can classified this nanocomposite as a hard magnet. And for the value of saturation magnetization is 1,07 memu and remanence magnetization is 0,35 memu. The applied field of nanocomposite shows in loop hysteresis with range -10000≤ H ≤10000, it show the ferromagnetic behavior. Ferromagnetic is one of material properties which needed for magnetic sensor. So can be concluded that MnFe2O4/PANi nanocomposite can be applied for magnetic sensor.

Full Text:

PDF

References


Sriyanti, Ida. 2009. Nanocomposite prepared by simple mixing method. Proceeding Of The Third International Seminar On Science Education. Palembang: Universitas Sriwijaya.

Rajab, La Agusu, dan La Ode Ngkoimani. 2017. Sintesis Nanopartikel Manganese Ferrite (MnFe2O4) Berbasis Pasir Besi dan Mangan Alam dengan Metode Reaksi Padatan.

Yunasfi, Indri Racmawati, Mashadi, Wisnu Ari Adi dan Nurmaya Arofah. 2018. Analisis Fasa Sistem Mn(1-X)NdxFe2O4 Sebagai Kandidat Bahan Penyerap Gelombang Mikro. Jurnal Metalurgi, Vol. 33, No.2, E-ISSN 2443-3926; 55 – 60.

Ghobadi, Misagh, dkk. 2018. MnFe2O4-graphene oxide magnetic nanoparticles as a high-performance adsorbent for rare earth elements: Synthesis, isotherms, kinetics, thermodynamics and desorption. Journal of Hazardous Material Vol 351. State University of New York

Dong XM, Fu RW, Zhang MQ, Zang B, Rong MZ. 2004. Electrical Resistance Response Of Carbon Black Filled Amorphouse Polymer Composite Sensors To Organic At Low Vapor Concentrations. Carbon 42(12-13);2551-9.

Nasution, dkk. 2012. Sintesis Nanokomposit Pani/Fe3O4 Sebagai Penyerap Magnetik Pada Gelombang Mikro. Jurnal Fisika Unand Vol. 1 No.1. Padang: Universitas Andalas.

Zeng, Shuang. Dkk. 2016. Magnetically recyclable MnFe2O4/polyaniline composite with enhanced visible light photocatalytic activity for rhodamine B degradation. China: Department of Chemistry, Jinan University.

Arsalani, Nasser, dkk. 2018. Novel PANI/MnFe2O4 nanocomposite for low-cost supercapacitors with high rate capability. Journal of Materials Science: Materials in Electronics. Faculty of Chemistry, University of Tabriz: Iran.

Darvina, Y., Rianto, D., Murti, F., Yulfriska, N., Ramli. 2017. Struktur Nano Partikel Oksida Besi dari Pasir Besi Pantai Tiram Sumatera Barat. Seminar Prosiding. Padang: Universitas Negeri Padang

Rianto, Debi, N Yulfriska, F Murti, H Hidayati, R Ramli. 2018. Analysis of Crystal Struktur of Fe3O4 Thin Films Based on Iron Sand Growth by Spin Coating. Methoe Journal of IOP Confrence Series Material Science and Engineering 335 012012

Rahmayeni, Yeni Stiadi, Zulhadjri. 2013. Fotokatalis Komposit Magnetik TiO2-MnFe2O4. Prosiding Semirata FMIPA Universitas Lampung. 339-344.

Khairy M, M.E Gounda.2014. Electrical And Optical Properties Of Nickel Ferrite/Polyaniline Nanocomposite. Journal Of Advance Reaserch (2014) 6(4):555-62

Helmita. 2018. Pengaruh Variasi Komposisi NiFe2O4 Terhadap Sifat Magnetik NANOKOMPOSIT NiFe2O4/PANi Yang Disintesis Dengan Metode Sol-Gel Spin Coating. Skripsi. Padang: Universitas Negeri Padang

Eken, A. E., Ozenbas, M. 2009. Characterization of nanostructured magnetite thin films produced by sol–gel processing. Journal Sol-Gel Sci Technol. 50:321–327

Tang, N.J, dkk. 2004. Nanostructured Magnetite (Fe3O4) Thin Films Prepared by Sol–gel Method. Nanjing University : China

Joshi, Seema, dkk. 2014. Structural, magnetic, dielectric and optical properties of nickel ferrite nanoparticles synthesized by co-precipitation method. Journal of Molecular Structure 1076. Jaypee Institute of Information Technology, India.

Susmita, Ria, dkk. 2013. Analisis Sifat Listrik Komposit Polianilin (PANi) Terhadap Penambahan Bottom Ash Sebagai Elektroda Superkapasitor. Jurnal Fisika Unand Vol. 2, No. 2. Padang: Universitas Andalas.

Jacintha, A. M. 2017. Synthesis and comparative studies of MnFe2O4 nanoparticles with different natural polymers by sol-gel method: structural, morphological, optical, magnetic, catalytic and biological activity. Journal of Nanostructure in Chemistry. Varuvan Vadivelan Institute of Technology India.

Jamal, M dan Ramli. 2011. Development of Sensors Based on Giant Magnetoresistance Material. Procedia Engineering 32: 60 – 68. Bandung : Institute teknologi Bandung

Khairunnisa Hafsah .2017. Pengaruh Penambahan Fe Pada Pembuatan Bonded Magnet NdFeB Terhadap Sifat Fisis Dan Sifat Magnet. Skripsi. Medan: Universitas Sumatera Utara.

Simamora Pintor, Krisna.2014. Sintesis Dan Karakterisasi Sifat Magnetik Nanokomposit Fe3O4-Montmorilonit Berdasarkan Variasi Suhu. Skripsi. Medan: Universitas Sumatera Utara.

Bertotti, G. 1998. Hysteresis In Magnetism, 1st Edition. Academic Press: USA.

Jayanti, N.D, dkk. 2013. Fabrikasi Magnet Komposit Berbahan Dasar Magnet Daur Ulang Dengan Pengikat Cult. Unnes Physics Journal. Semarang: Universitas Negeri Semarang.




DOI: http://dx.doi.org/10.24036/7535171074