The Effect of Go Composition Variation on The Optical Properties of ZnO/GO Thin Films as a Candidate Material for Solar Cells

- Maharani - Departement of physics, Universitas Negeri Padang, Jl. Prof. Dr. Hamka Air Tawar Padang 25131
Riri Jonuarti - Departement of physics, Universitas Negeri Padang, Jl. Prof. Dr. Hamka Air Tawar Padang 25131
- Ratnawulan - Departement of physics, Universitas Negeri Padang, Jl. Prof. Dr. Hamka Air Tawar Padang 25131
Rahmat Hidayat - Departement of physics, Universitas Negeri Padang, Jl. Prof. Dr. Hamka Air Tawar Padang 25131

Abstract


This study aims to investigate the effect of Graphene Oxide (GO) composition variation on the optical and electronic properties of ZnO/GO thin films, which have potential as candidate materials for solar cells. The synthesis method employed is sol-gel, followed by the spin coating technique to produce thin films on glass substrates. Characterization was carried out using X-Ray Diffraction (XRD) to determine the crystalline structure, Scanning Electron Microscopy (SEM) for morphological analysis, and UV-Vis spectroscopy to measure optical properties, including light absorption and band gap.  The results indicate that a 3% GO composition significantly affects the optical and electronic properties of ZnO/GO. The addition of GO enhances light absorption in both the UV and visible ranges and reduces the band gap, contributing to improved energy conversion efficiency. Furthermore, SEM characterization shows a better particle distribution at 3% GO compared to other compositions, enhancing the interaction between ZnO and GO. Based on these findings, it can be concluded that a ZnO/GO combination with 3% GO has good potential as a material for solar cell applications. This research is expected to contribute to the development of more efficient and environmentally friendly renewable energy materials

References


​M. Farghali et al., Strategies to save energy in the context of the energy crisis: a review, vol. 21, no. 4. Springer International Publishing, 2023. doi: 10.1007/s10311-023-01591-5.

​W. S. Ebhota and T. C. Jen, “Fossil Fuels Environmental Challenges and the Role of Solar Photovoltaic Technology Advances in Fast Tracking Hybrid Renewable Energy System,” Int. J. Precis. Eng. Manuf. - Green Technol., vol. 7, no. 1, pp. 97–117, 2020, doi: 10.1007/s40684-019-00101-9.

​Q. Hassan et al., “The renewable energy role in the global energy Transformations,” Renew. Energy Focus , vol. 48, no. August 2023, p. 100545, 2024, doi: 10.1016/j.ref.2024.100545.

​M. B. Hayat, D. Ali, K. C. Monyake, L. Alagha, and N. Ahmed, “Solar energy—A look into power generation, challenges, and a solar-powered future,” Int. J. Energy Res., vol. 43, no. 3, pp. 1049–1067, 2019, doi: 10.1002/er.4252.

​C. Luan, X. Sun, and Y. Wang, “Driving forces of solar energy technology innovation and evolution,” J. Clean. Prod., vol. 287, no. xxxx, p. 125019, 2021, doi: 10.1016/j.jclepro.2020.125019.

​C. Lee, S. Lee, G. U. Kim, W. Lee, and B. J. Kim, “Recent Advances, Design Guidelines, and Prospects of All-Polymer Solar Cells,” Chem. Rev., vol. 119, no. 13, pp. 8028–8086, 2019, doi: 10.1021/acs.chemrev.9b00044.

​M. V. Dambhare, B. Butey, and S. V. Moharil, “Solar photovoltaic technology: A review of different types of solar cells and its future trends,” J. Phys. Conf. Ser., vol. 1913, no. 1, 2021, doi: 10.1088/1742-6596/1913/1/012053.

​K. Valadi, S. Gharibi, R. Taheri-Ledari, S. Akin, A. Maleki, and A. E. Shalan, “Metal oxide electron transport materials for perovskite solar cells: a review,” Environ. Chem. Lett., vol. 19, no. 3, pp. 2185–2207, 2021, doi: 10.1007/s10311-020-01171-x.

​M. Xiao et al., “Hollow Nanostructures for Photocatalysis: Advantages and Challenges,” Adv. Mater., vol. 31, no. 38, 2019, doi: 10.1002/adma.201801369.

​B. Wang et al., “The charge carrier dynamics, efficiency and stability of two-dimensional material-based perovskite solar cells,” Chem. Soc. Rev., vol. 48, no. 18, pp. 4854–4891, 2019, doi: 10.1039/c9cs00254e.

​D. K. Sharma, S. Shukla, K. K. Sharma, and V. Kumar, “A review on ZnO: Fundamental properties and applications,” Mater. Today Proc., vol. 49, no. xxxx, pp. 3028–3035, 2020, doi: 10.1016/j.matpr.2020.10.238.

​X. Wang, D. Yu, and S. Xu, “Determination of absorption coefficients and Urbach tail depth of ZnO below the bandgap with two-photon photoluminescence,” Opt. Express, vol. 28, no. 9, p. 13817, 2020, doi: 10.1364/oe.391534.

​H. J. Seul et al., “Atomic Layer Deposition Process-Enabled Carrier Mobility Boosting in Field-Effect Transistors through a Nanoscale ZnO/IGO Heterojunction,” ACS Appl. Mater. Interfaces, vol. 12, no. 30, pp. 33887–33898, 2020, doi: 10.1021/acsami.0c06382.

​C. Zhu et al., “Graphene oxide humidity sensor with laser-induced graphene porous electrodes,” Sensors Actuators, B Chem., vol. 325, no. August, p. 128790, 2020, doi: 10.1016/j.snb.2020.128790.

​N. Mariotti et al., “Recent advances in eco-friendly and cost-effective materials towards sustainable dye-sensitized solar cells,” Green Chem., vol. 22, no. 21, pp. 7168–7218, 2020, doi: 10.1039/d0gc01148g.

​G. Bagha, M. R. Mersagh, H. Naffakh-Moosavy, and L. F. Matin, “The role of rGO sheet and Ag dopant in reducing ZnO electron transport layer recombination in planar perovskite solar cells,” Ceram. Int., vol. 47, no. 11, pp. 16111–16123, 2021, doi: 10.1016/j.ceramint.2021.02.186.

​N. E. Safie, M. A. Azam, M. F. A. Aziz, and M. Ismail, “Recent progress of graphene-based materials for efficient charge transfer and device performance stability in perovskite solar cells,” Int. J. Energy Res., vol. 45, no. 2, pp. 1347–1374, 2021, doi: 10.1002/er.5876.

​V. S. Kindalkar, K. M. Sandeep, K. Kumara, and S. M. Dharmaprakash, “Sol-gel synthesized spin coated GO: ZnO composite thin films: Optical, structural and electrical studies,” Mater. Res. Express, vol. 6, no. 9, 2019, doi: 10.1088/2053-1591/ab3164.

​P. M. Podsakoff and N. P. Podsakoff, “Experimental designs in management and leadership research: Strengths, limitations, and recommendations for improving publishability,” Leadersh. Q., vol. 30, no. 1, pp. 11–33, 2019, doi: 10.1016/j.leaqua.2018.11.002.

​H. Taherdoost, “Data Collection Methods and Tools for Research; A Step-by-Step Guide to Choose Data Collection Technique for Academic and Business Research Projects Hamed Taherdoost. Data Collection Methods and Tools for Research; A Step-by-Step Guide to Choose Data Collection Technique for Academic Data Collection Methods and Tools for Research; A Step-by-Step Guide to Choose Data Collection Technique for Academic and Business Research Projects,” Int. J. Acad. Res. Manag., vol. 2021, no. 1, pp. 10–38, 2021, [Online]. Available: https://hal.science/hal-03741847

​N. Danyliuk, T. Tatarchuk, and A. Shyichuk, “Estimation of photocatalytic degradation rate using smartphone based analysis,” Phys. Chem. Solid State, vol. 21, no. 4, pp. 727–736, 2020, doi: 10.15330/PCSS.21.4.727-736.

​G. Pérez-Zúñiga, G. Herrera-Pérez, Y. Verde-Gómez, and A. M. Valenzuela-Muñiz, “Self-assembled ZnO-rGO nanocomposite, a solid-state transformation to control its crystallite size,” J. Alloys Compd., vol. 875, p. 159992, 2021, doi: 10.1016/j.jallcom.2021.159992.

​T. Chitradevi, A. Jestin Lenus, and N. Victor Jaya, “Structure, morphology and luminescence properties of sol-gel method synthesized pure and Ag-doped ZnO nanoparticles,” Mater. Res. Express, vol. 7, no. 1, 2019, doi: 10.1088/2053-1591/ab5c53.




DOI: http://dx.doi.org/10.24036/16848171074